HERCULES CHEMICAL CO INC -- WHAM -- 6850-00N038712
===================== Product Identification ===================== Product ID:WHAM MSDS Date:02/26/1987 FSC:6850 NIIN:00N038712 === Responsible Party === Company Name:HERCULES CHEMICAL CO INC Address:29 WEST 38 ST City:NEW YORK State:NY ZIP:10018-5595 Country:US Info Phone Num:212-869-4330 Emergency Phone Num:212-869-4330 CAGE:84794 === Contractor Identification === Company Name:HERCULES CHEMICAL CO INC Address:111 SOUTH STREET(OLD IS 29 W 38 ST) Box:City:PASSAIC State:NJ ZIP:07055-7398 Country:US Phone:973-778-5000 CAGE:84794 ============= Composition/Information on Ingredients ============= Ingred Name:BENZOIC ACID, METHYL ESTER; (METHYL BENZOATE) CAS:98-58-3 RTECS #:DH3850000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE/CHRONIC: NONE; EVAULATED AS A SKIN SENSITIZING CHEMICAL AND FOUND TO BE NEGATIVE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:MILD EYE IRRITANT AND MILD SKIN IRRITANT. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH W/PLENTY OF LOW PRESS WATER FOR @ LST 15 MIN. REMOVE ANY CONT LENSES TO ASSURE THOROUGH FLUSHING. CALL A PHYS. SKIN: PROMPTLY FLUSH W/RUNNING WATER. REMOVE CONTAMD CLTHG. WASH CLTHG BEFORE REUSE. INGEST: IF CONSCIOUS, PERSON SHOULD IMMED DRINK LG QTY OF LIQ TO DILUTE PROD. NEVER GIVE LIQ TO AN UNCON PERSON. DO NOT INDUCE VOMIT. CALL A PHYS IMMED. NOTE TO PHYS: REMOVE (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:180F,82C Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM, OR CARBON DIOXIDE. Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. CLOSED CONTAINERS (DRUMS) EXPOSED TO FIRE SHOULD BE COOLED BY A WATER SPRAY TO AVOID PRESS BUILD-UP. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:EXTING SOURCE OF IGNIT. DIKE TO CONTAIN. PUMP INTO CLEAN, COVERED STEEL DRUMS FOR DISPOSAL. SMALL SPILL ABSORB WITH VERMICULITE OR ABSORB MATERIAL AND PICK UP FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM IGNITION SOURCES SUCH AS SPARKS AND OPEN FLAME. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS WHEN VENTILATION IS INADEQUATE. Ventilation:LOCAL EXHAUST: ADEQUATE. Protective Gloves:NEOPRENE/BUNA-N. Eye Protection:CHEMICAL WORKERS GOGGLES . Work Hygienic Practices:USE GOOD PERSONAL HYGIENE PRACTICES, WASH AFTER HANDLING. Supplemental Safety and Health FIRST AID PROC: FROM STOMACH BY GASTRIC LAVAGE. ASPIRATION MAY CAUSE HYDROCARBON PNEUMONIA. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>388F,>198C Vapor Pres:1 Vapor Density:4.7@102F Spec Gravity:1.09(H*2O=1) Evaporation Rate & Reference:1(BUTYL ACETATE=1) Solubility in Water:SLIGHTLY MISCIBLE Appearance and Odor:COLORLESS LIQUID. STRONG FRAGRANT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT AND OPEN FLAME. Hazardous Decomposition Products:METHANOL UPON HYDROLYSIS; CARBON DIOXIDE AND MONOXIDE ON COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL SPILL NON-HAZARDOUS LANDFILL. LARGE SPILLS NOT LISTED IN FEDERAL, BUT CHECK APPLICABLE STATE AND LOCAL WASTE REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.